Photocatalytic H2Evolution from Oxalic Acid: Effect of Cocatalysts and Carbon Dioxide Radical Anion on the Surface Charge Transfer Mechanisms
Photocatalytic reforming of carboxylic acids on cocatalyst-loaded semiconductors is an attractive process for H2 generation that has been studied for years. Experimental support for the surface reaction mechanisms, nevertheless, is still insufficient. Herein, the mechanism of the photocatalytic conversion of oxalic acid in anaerobic conditions together with the total yields have been deeply investigated by
A comprehensive energy and exergoeconomic analysis of a novel transcritical refrigeration cycle
A comprehensive energy and exergoeconomic analysis of a novel transcritical refrigeration cycle (NTRC) is presented. A second ejector is introduced into the conventional refrigeration system for the utilization of the gas-cooler waste heat. The thermodynamic properties of the working fluid are estimated by the database of REFPROP 9, and a FORTRAN program is used to
Operational mode optimization of indirect evaporative cooling in hot climates
This study experimentally investigates the performance of an indirect evaporative cooling fresh air-handling unit at different modes of operation under harsh climatic conditions experienced in Qatar. Temperature and relative humidity are measured at various points within the fresh air handling unit for each mode of operation and, the measured data are stored and analyzed. Cooling
Experimental analysis of mist injection and water shower indirect evaporative cooling in harsh climate
An experimental investigation of the performance of a direct-indirect evaporative cooling fresh air handling unit with different modes of operation is presented. Linear regression analysis is used to fit the experimental results, and the correlation coefficient is evaluated. It is found that the highest temperature reduction of 18.8°C is achieved across the heat exchanger for
Experimental analysis of the cooling performance of a fresh air handling unit
An experimental investigation of the performance of a fresh air handling unit integrating indirect evaporative and vapor compression cooling is conducted. Temperature and relative humidity measurements at main points within the cooling unit were logged using a wireless data acquisition system. Experimental data downloaded from the acquisition system is used for linear regression analysis, and
Stabilisation of α′ dicalcium silicate in calcium sulfoaluminate clinker
Calcium sulfoaluminate cements are widely used as special cements and, because of their low specific carbon dioxide emissions relative to those of Portland cement, they have potential for use in general construction. However, their widespread application has been limited by the relatively high cost of aluminous raw materials. As part of a broad programme on
Techno-economic assessment of a carbon capture and utilization process for the production of plaster-like construction materials
In the context of the decarbonisation of the building sector, this work focuses on the process economics of a carbon capture and utilization alternative for the production of a novel construction material based on magnesium carbonate trihydrate, also known as nesquehonite. This material, after a dehydration-rehydration process, can be conformed into moulds with a significant
Exploring Floriculture Potential for Sustainable Livelihood of Subsistence Communities in Indian Himalaya
The present paper describes the impact of floriculture on socio-economic development of the rural communities inhabited in the Himalayan Mountains. Rural and traditional societies are interested and many are involved in floriculture business for supplementing their livelihood for sustainability in the region. Keeping this in view, two varieties of potential flowers viz. Gladiolus and Lilium
Performance assessment of a hybrid vapor compression and evaporative cooling fresh-air-handling unit operating in hot climates
Evaporative cooling can be integrated into fresh-air-handling units, to reduce cooling demand. This study considers a hybrid fresh-air-handling unit which incorporates a vapor-compression cooling cycle and indirect evaporative cooling to condition an ambient primary airstream to a desired supply air state. The cooling eects of using various modes (vapor compression only; direct expansion with mist;
Assessing the water energy nexus and sustainability benefits of a closed loop water treatment system in Qatar
Qatar has very limited freshwater resources. This paper assesses the sustainability implications of using bore water and treated sewage effluent (TSE) for residential water supply (for non-drinking purposes) in a residential compound in Doha, Qatar. The treated bore water was considered for non-drinking domestic applications in kitchens and bathrooms, while the TSE was considered for
Photocatalytic Functionalized Aggregate: Enhanced Concrete Performance in Environmental Remediation
Engineering of effective photocatalytically active structures is of great importance as it introduces a solution for some existing air pollution problems. This can be practically achieved through the bonding of particulate photocatalysts to the surface of construction materials, such as aggregates, with a suitable stable binding agent. However, the accessibility of the photocatalytically active materials
Techno-economic and Environmental Implications of the Use of a Closed Loop Water Recycling System in Qatar
This paper presents the environmental and economic benefits from the use of potable water from a desalination plant, and treated sewage effluent (TSE) for non-potable reuse, in Lusail, Doha. This newly built city plans to use TSE for a large portion (98 %) of its non-domestic applications instead of discharging TSE to the ocean. It
Seed maturation time influences the germination requirements of perennial grasses in desert climate of Arabian Gulf
Qatar has a dry, subtropical desert climate, with minimum annual rainfall and intensely hot and humid summers. Using indigenous grass, those adapted to local conditions have the potential to be used for fodder and can also be used for restoration or rehabilitation of degraded rangelands. Chloris virgata, Coelachyrum brevifolium and Cenchrus ciliaris bloom twice a
The Conversion of Magnesium Carbonates into Plaster-Like Products: A Preliminary Study of the Hardening Mechanism
Magnesium carbonate trihydrate, nesquehonite, is proposed as a precursor for the production of a construction material similar to plasterboard, in a unique carbon capture and utilisation process [1]. The hardening process is thought to follow a similar mechanism to gypsum in the manufacture of plasterboard, where the hardening is produced in the recrystallization of gypsum
Conceptual design of a CO2 capture and utilisation process based on calcium and magnesium rich brines
Carbon capture and utilisation processes, CCU, are those processes aiming to produce usable products from CO2-based materials. Although there are a large number of CCU alternatives, only a few are able to propose routes for the massive production of marketable CO2 based products with a negative or neutral carbon footprint in the long term. In
Germination Patterns of Dimorphic Achenes in Launaea nudicaulis (Asteraceae) Growing in Desert Environments
Launaea nudicaulis (Asteraceae) produces two morphologically distinct types of achenes (whitish brown and black) in a single capitulum. All L. nudicaulis achenes have a pappus and pappi were removed artificially in this study for experimental purposes. The germination of achenes of both colours, with and without pappi, under various temperature regimes and illumination conditions was